Tech Alerts May 2023
Abstracts that tickle this reviewer's interest
Courtesy of Google Scholar
Year - Month: 2023-05
DJ Gardner, G Pokhrel, A Collins - Biobased Adhesives: Sources, Characteristics and …, 2023
This chapter covers the adhesion theories in naturally‐based adhesive bonding and
adhesion and surface issues with naturally‐based adhesives. Chemicals and
polymers derived from nature have been used as adhesives for thousands of years …
Adhesive Precursors from Tree‐Derived Naval Stores
CR Frihart - Biobased Adhesives: Sources, Characteristics and …, 2023
… Terpene uses have a long history as a naval stores products; they were originally
collected mainly by the condensation of the volatiles from the destructive heating of
wood in a confined space to yield turpentine, a very useful solvent, and residual pitch …
Chuck worked in my group at the Union Camp Princeton R & D Lab. He’s done well at the Forest Products Lab in Madison.
Adhesive Precursors from Tree‐Derived Naval Stores
CR Frihart - Biobased Adhesives: Sources, Characteristics and …, 2023
… Obviously, this process for gum rosin is labor intensive and gum rosin is mainly
produced in Asia; gum rosin is still used despite its higher price due to superior
properties compared to competing wood and tall oil rosins. In the 1800s, wood rosin …
Adhesive Precursors from Tree‐Derived Naval Stores
CR Frihart - Biobased Adhesives: Sources, Characteristics and …, 2023
… The common terpenes are all Biobased and include α-pinene and β-pinene from
sulfate turpentine and limonene (dipentene) from orange peels (see Figure 18.11).
The terpenes when polymerized by cationic solution polymerization with heat and a …
Adhesive Precursors from Tree‐Derived Naval Stores
CR Frihart - Biobased Adhesives: Sources, Characteristics and …, 2023
… The most important current commercial products are gum, wood, and tall oil
rosins (TORs), tall oil fatty acids (TOFAs) and terpenes, the latter three of which are
by-products of the Kraft wood pulping process of pine trees in the southeastern US …
Epoxy Adhesives from Natural Materials
CR Frihart - Biobased Adhesives: Sources, Characteristics and …, 2023
… The particular Biobased fatty acid that is used is tall oil fatty acid (TOFA), which is
isolated as a by-product of wood pulping using the Kraft process (see chapter 18 “Adhesive
Precursors from Tree-Derived Naval Stores” in this book) and [15]. These have been …
HM Chi, P Hu, SA Snyder - Chem, 2023
… Although the structural diversity of the natural products that can be derived from
terpene building blocks is nothing short of incredible, the methods by which nature
folds these pieces together and forges new C–C bonds leading to rings and chiral …
[HTML]Review of Corrosion Inhibitors in Reinforced Concrete: Conventional and Green Materials
A Zomorodian, A Behnood - Buildings, 2023
… Generally the long-chain fatty acids, such as oleic acid, soya fatty acid, and tall oil
fatty acid (TOFA), have been well recognized as corrosion inhibitors, but short-chain
fatty acids may accelerate corrosion [11]. Ormellese et al. evaluated the nine most …
Metal ions recognition and DNA binding properties of fourrosinderivatives
CN Hui, LY Kong, JY Long, BL Fei - Chemical Physics, 2023
… is an advantageous natural product resource in China; the organic derivatives of
rosin are widely used in … We try to provide experimental basis for the utilization of
rosin derivatives. … These results obtained from this work will be helpful in the …
Auto-Catalytic Epoxidation of Oleic Acid Derived from Palm Oil Via In Situ Performed Acid Mechanism
HH Habri, IS Azmi, NM Mubarak, MJ Jalil - Catalysis Surveys from Asia, 2023
The use of renewable materials in the epoxidation reaction has gained increasing
attention due to the need to reduce reliance on non-renewable resources and
minimize environmental impact. To date, there is a paucity of studies on the …
[PDF]Renewable diesel Production: A Review
I Edeh, AB Raheem - Petro Chem Indus Intern, 2023
Biodiesel is considered an alternative to petroleum diesel as it is more
environmentally friendly, cleaner, decreases greenhouse gas emissions, non toxic
and biodegradagable. Although, low energy density, relatively high cost of …
Failure mechanism of temperature measuring tube in hydrogenatedrosinmethyl ester reaction kettle
X Hu, Z Li, Y Luo, X Han, Z Zhang - Engineering Failure Analysis, 2023
Hydrogenated rosin methyl ester (HRME) reaction kettle has been widely used in
food, medicine, chemical industry. This article analyses the penetration crack failure
of the temperature-measuring tube on the HRME reactor, which is made of 316L and …
MJ Park, BM An, D Lee, JM Choi, YH Choi, BS Joo - 생명과학회지, 2023
The underlying action of policosanol in lowering cholesterol level has not yet been
clearly elucidated. Several recent studies have suggested that sterol regulatory
element-binding proteins (SREBP)-1c play a role in the regulation of cholesterol …
[HTML]New method for isolating β-sitosterol from bleaching effluent of sulphite pulp mill
DD Evtyugin, A Prates, MR Domingues, S Casal… - Food and Bioproducts …, 2023
… When ethanol was used instead, BS was detected in low amounts in the isolate,
being fatty acid sterol esters and fatty acid glycerides the major … The method is
adaptable for large-scale industrial production of BS and may represent an …
[PDF]A Cooperative Rh/Co‐catalyzed Hydroaminomethylation Reaction for the Synthesis ofTerpeneAmine
A Pérez Alonso, D Pham Minh, D Pla, M Gómez - ChemCatChem
An original bimetallic catalytic system based on Rh(I) and Co(0) in glycerol is
described for the synthesis of biomass‐derived amines through the tandem
hydroaminomethylation reaction of terpenes, such as (R)‐limonene, b‐pinene and …
[PDF]CATIONIC OVER-STABILISED BITUMEN EMULSION IN ROAD CONSTRUCTION-REVIEW
I Sidun, K Sobol, V Bidos, O Hunyak, I Protsyk
This article describes the classification of cationic bitumen emulsions according to"
reactivity" and breaking behaviour characteristics. The methods of researching the
characteristics of breaking behaviour for bitumen emulsions of different" reactivity" in …
Self healing approaches in polymeric materials-an overview
S Parihar, B Gaur - Journal of Polymer Research, 2023
… -reversible self-healing coating materials derived from gum rosin, a pine tree
product [67]. The self-healing is attained by using Diels-Alder chemistry. Furfuryl
amine is the diene moiety that has been introduced into the gum rosin-based resin …
Viscoelastic parametric conversions and mechanical response analysis of asphalt mixtures
T Bai, X Huang, X Zheng, H Wang, Y Cheng, B Cui… - Construction and Building …, 2023
In this study, dynamic modulus, dynamic resilience modulus, and creep compliance
tests were conducted to characterize and quantify the effects of viscoelastic
parameters of asphalt mixtures on the mechanical response of pavement structures …
Complex, but useful for the development of additives for asphalt
[PDF]Menthol Oxidation to Menthone: An Important Chemical Transformation
MFLP Carlos, MVN de Souza - General Chemistry
Abstract: Oxidation is a key transformation in chemistry being involved in a wide
range of processes. In natural products, this reaction plays a critical role in the
biosynthesis of several classes from different sources. In this context, the oxidation of …
S Nazir, WA Chaudhary, A Mubashar, I Anjum… - Pakistan Journal of Health …, 2023
… A fundamental form of sterol called Campesterol contains a hydroxyl group
situated at position C-3 in its steroid skeleton. The sterol … Campesterol (CAS 474-62-4)
is classi ed as a member of Phytosterols, which is characterized as a 3betasterol, a …
[PDF]A new experimental methodology for assessing adhesive properties
PRB Kozowykº, JA Poulis
… However, we will continue using “tar" for simplicity and because “pitch' is also
used to refer to gum rosin from conifers. The furnace was programmed to mimic the
heating cycle of the most successful raised structure tar production experiment …
Tech Alerts May 2023 Thompson
RUBBER COMPOSITION FOR TIRES AND PNEUMATIC TIRE
European Patent EP3597696 B1 · Filed: 04/13/2018 · Published: 05/17/2023
Assignee:
SUMITOMO RUBBER IND (Kobe-shi, Hyogo 651-0072, JP)
Inventors:
KITAURA TAKEHIRO (JP)
TOYA SUBARU (JP)
YOSHIYASU HAYATO (JP)
YAMADA HIROAKI (JP)
This patent application is another example of improving the abrasion resistance of tire rubbers using small amounts of tetrazine compounds. A plausible mechanism is the tetrazines reacting with the rubber in a Diels Alder manner to cross link it, i.e. click chemistry. Tetrazines are 6-membered aromatic rings with molecular formula C2H2N4.
MODIFIED RESINS AND USES THEREOF
European Patent EP3606992 B1 · Filed: 04/02/2018 · Published: 05/17/2023
Assignee:
CONTINENTAL REIFEN DEUTSCHLAND GMBH (30165 Hannover, DE)
SYNTHOMER ADHESIVE TECH LLC (Beachwood, Ohio 44122, US)
Inventors:
ARIGO MARK (US)
CARVAGNO TERRI ROXANNE (US)
DE HULLU JACOBUS GILLIS (NL)
FINGER SEBASTIAN (DE)
HIRSCHLAG HUBERT (DE)
KLOMP JANINE (NL)
PETERS FABIAN (DE)
RECKER CARLA (DE)
ROBERTSON CHRISTOPHER GEORGE (US)
VERSLUIJS PETER (NL)
This patent describes the use of removing significant amounts of dimers, trimers, tetramers, and pentamers (what we call “dimer oil”) from resins so as to significantly reduce the resin’s Mn while producing a modified Mz that is very close to that of the starting resin. In other words, “high Mn/high %dimer oil” to “less dimer oil/lower Mn/similar Mz”. Such compositional changes, which can often be accomplished with separation procedures like wiped film evaporators, produce different properties than can be made with the so-called traditional run-down techniques. Examples of these modified resins were tested in adhesives and tire rubbers and the like.
Well worth the time to read and study this patent. Standard analytical procedures are given along with measurements of basic properties of the resins.
A RUBBER COMPOSITION
WIPO Patent Application WO/2023/073905 A1 · Filed: 10/29/2021 · Published: 05/04/2023
Assignee:
MICHELIN & CIE (FR)
Inventors:
MAETA YOSHIKO (JP)
MAYER SYLVAIN (FR)
RIOU ALINE (FR)
A rubber composition, which allows unexpectedly improved efflorescence performance without deteriorated ozone resistance performance, is based on an elastomer matrix; a reinforcing filler, an anti-ozone wax, and a crumb rubber. Anti-ozone agents form films on the surface of polymers like tires that block attack by ozone. Apparently, the inventors discovered a polymer-based formulation that forms a surface deposit that still has resistance to ozone.
PROCESS FOR PREPARING LIMONENE AND COMPOSITION CONTAINING LIMONENE
United States Patent Application 20230144944 A1 · Filed: 02/18/2020 · Published: 05/11/2023
Assignee:
SYMRISE AG (Holzminden, DE)
Inventors:
Bugdahn, Nikolas (Holzminden, DE)
Köckritz, Angela (Berlin, DE)
Kraleva, Elka (Rostock, DE)
Eckelt, Reinhard (Rostock, DE)
This application claims a catalytic conversion of beta-pinene (or high beta-pinene containing feeds) to limonene using a trickle-down reactor bed and acidic catalysts to achieve unprecedented results. This is a good read as an example of project planning.
Method To Prepare An Aviation Fuel Component
United States Patent Application 20230134111 A1 · Filed: 11/23/2020 · Published: 05/04/2023
Assignee:
Neste Oyj (Espoo, FI)
Inventors:
Kiiski, Ulla (Porvoo, FI)
Likander, Salla (Porvoo, FI)
Sandberg, Kati (Porvoo, FI)
Saikkonen, Pirjo (Porvoo, FI)
This application claims a process to produce aviation fuel starting with tall oil pitch (TOP-our sterols feed for Arboris). As you can see, the scheme involves a number of fractions and potentially a lot of tanks. One thing I noticed is that the analyses of various fractions from TOP were done in 1978. Is there no up- to-date analytical work available?
Sulfonated Lignin-Derived Compounds and uses Thereof
United States Patent Application 20230160143 A9 · Filed: 02/17/2021 · Published: 05/25/2023
Assignee:
CMBlu Energy AG (Alzenau, DE)
Inventors:
Krawczyk, Nastaran (Giessen, DE)
Moeller, Alexander (Giessen, DE)
Geigle, Peter (Alzenau, DE)
Larionov, Evgeny (Alzenau, DE)
Hartwig, Jan (Alzenau, DE)
“The present invention relates to novel lignin-derived compounds and compositions comprising the same and their use as redox flow battery electrolytes. The invention further provides a method for preparing said compounds and compositions as well as a redox flow battery comprising said compounds and compositions. Additionally, an assembly for carrying out the inventive method is provided.”
My comments. The sulfonated quinone compounds of interest here are by-products of the sulfite pulping of wood. These quinones have the capability to store electrical energy better than metal based redox-flow batteries. Time will tell how this development pans out. It is interesting though. Btw the sulfite pulping process has been around forever (Ingevity supposedly has used it but I’m not sure of it) but the chemistry is old. Electrical energy storage could be a very useful outlet.
Courtesy of Kerry Thompson, Nelson Lawson, and the PCA.